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AMITROLE

ICSC: 0631

1,2,4-Triazol-3-ylamine
3-Amino-1H-1,2,4-triazole
Aminotriazole
C2H4N4
Molecular mass: 84.1
ICSC # 0631 		CAS # 61-82-5
RTECS # XZ3850000
UN # 2588
EC # 613-011-00-6
April 20, 1994 Validated

TYPES OF HAZARD/ EXPOSURE

ACUTE HAZARDS/ SYMPTOMS

PREVENTION

FIRST AID/
FIRE FIGHTING

FIRE Not combustible. Gives off irritating or toxic fumes (or gases) in a fire.

In case of fire in the surroundings: use appropriate extinguishing media.
EXPLOSION


EXPOSURE
STRICT HYGIENE!

•INHALATION
Ventilation (not if powder), local exhaust, or breathing protection.
Refer for medical attention.
•SKIN
Protective gloves. Protective clothing.
Remove contaminated clothes. Rinse skin with plenty of water or shower.
•EYES
Face shield or eye protection in combination with breathing protection if powder.
First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
•INGESTION
Do not eat, drink, or smoke during work. Wash hands before eating.
Rinse mouth. Induce vomiting (ONLY IN CONSCIOUS PERSONS!). Refer for medical attention.

SPILLAGE DISPOSAL

STORAGE

PACKAGING & LABELLING

Do NOT wash away into sewer. Sweep spilled substance into sealable containers; if appropriate, moisten first to prevent dusting. Carefully collect remainder, then remove to safe place. Personal protection: P3 filter respirator for toxic particles.
Separated from food and feedstuffs , incompatible materials . See Chemical Dangers. Keep in the dark. Keep in a well-ventilated room.
Do not transport with food and feedstuffs.
Severe marine pollutant.
Xn symbol
N symbol
R: 48/22-63-51/53
S: 2-13-36/37-61
UN Hazard Class: 6.1
UN Packing Group: III
ICSC: 0631 Prepared in the context of cooperation between the International Programme on Chemical Safety & the Commission of the European Communities (C) IPCS CEC 1994. No modifications to the International version have been made except to add the OSHA PELs, NIOSH RELs and NIOSH IDLH values.

AMITROLE

ICSC: 0631

I

M

P

O

R

T

A

N

T


D

A

T

A

PHYSICAL STATE; APPEARANCE:
ODOURLESS, COLOURLESS CRYSTALS.

PHYSICAL DANGERS:


CHEMICAL DANGERS:
The substance decomposes on heating producing toxic fumes 0f nitrogen oxides . The substance is a weak base. Reacts with strong acids , strong oxidants , acid chlorides and acid anhydrides . Attacks iron, copper and aluminium.

OCCUPATIONAL EXPOSURE LIMITS:
TLV: 0.2 mg/m3 as TWA; A3 (confirmed animal carcinogen with unknown relevance to humans); (ACGIH 2004).
MAK: (Inhalable fraction) 0.2 mg/m3;
Peak limitation category: II(8); Carcinogen category: 3B; Pregnancy risk group: C;
(DFG 2005).
OSHA PEL†: none
NIOSH REL: Ca TWA 0.2 mg/m3 See Appendix A
NIOSH IDLH: Ca N.D. See: IDLH INDEX


ROUTES OF EXPOSURE:
The substance can be absorbed into the body by inhalation of its aerosol and by ingestion.

INHALATION RISK:
Evaporation at 20°C is negligible; a harmful concentration of airborne particles can, however, be reached quickly on spraying or when dispersed, especially if powdered.

EFFECTS OF SHORT-TERM EXPOSURE:
The substance may cause effects on the thyroid .

EFFECTS OF LONG-TERM OR REPEATED EXPOSURE:
The substance may have effects on the thyroid , resulting in goitrogenic effects.

PHYSICAL
PROPERTIES

Melting point: 159°C
Solubility in water:
good
Octanol/water partition coefficient as log Pow: -0.65

ENVIRONMENTAL
DATA

This substance may be hazardous in the environment; special attention should be given to plants.

N O T E S

Temperature of decomposition unknown in literature. Depending on the degree of exposure, periodic medical examination is suggested. Card has been partly updated in October 2005. See sections Occupational Exposure Limits, EU classification, Emergency Response.
Transport Emergency Card: TEC (R)-61GT7-III

ADDITIONAL INFORMATION



ICSC: 0631 AMITROLE
(C) IPCS, CEC, 1994
IMPORTANT LEGAL NOTICE: Neither NIOSH, the CEC or the IPCS nor any person acting on behalf of NIOSH, the CEC or the IPCS is responsible for the use which might be made of this information. This card contains the collective views of the IPCS Peer Review Committee and may not reflect in all cases all the detailed requirements included in national legislation on the subject. The user should verify compliance of the cards with the relevant legislation in the country of use. The only modifications made to produce the U.S. version is inclusion of the OSHA PELs, NIOSH RELs and NIOSH IDLH values.
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