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Ammonium sulfamate

Synonyms & Trade Names
Ammate herbicide, Ammonium amidosulfonate, AMS [Ammonium sulfamate], Monoammonium salt of sulfamic acid, Sulfamate
CAS No.
7773-06-0
RTECS No.
WO6125000
DOT ID & Guide
Formula
NH₄OSO₂NH₂
Conversion
IDLH
1500 mg/m3
See: 7773060
Exposure Limits
NIOSH REL
TWA 10 mg/m3 (total) TWA 5 mg/m3 (resp)
OSHA PEL
TWA 15 mg/m3 (total) TWA 5 mg/m3 (resp) See Appendix G
Measurement Methods
NIOSH S348 (II-5)
See: NMAM or OSHA Methods
Physical Description
Colorless to white crystalline, odorless solid. [herbicide]
Molecular Weight
114.1
Boiling Point
320°F (Decomposes)
Melting Point
268°F
Solubility
200%
Vapor Pressure
0 mmHg (approx)
Ionization Potential
?
Specific Gravity
1.77
Flash Point
NA
Upper Exposive Limit
NA
Lower Explosive Limit
NA
Noncombustible Solid
Incompatibilities & Reactivities
Acids, hot water [Note: Elevated temperatures cause a highly exothermic reaction with water.]
Exposure Routes
inhalation, skin and/or eye contact
Symptoms
irritation eyes, nose, throat; cough, dyspnea (breathing difficulty)
Target Organs
Eyes, respiratory system
Personal Protection/Sanitation
(See protection codes)
Skin:No recommendation
Eyes:No recommendation
Wash skin:No recommendation
Remove:No recommendation
Change:No recommendation
First Aid
(See procedures)
Eye:Irrigate immediately
Skin:Soap wash promptly
Breathing:Respiratory support
Swallow:Medical attention immediately
Respirator Recommendations

NIOSH

Up to 50 mg/m3:
(APF = 5) Any quarter-mask respirator.
Click here for information on selection of N, R, or P filters.

Up to 100 mg/m3:
(APF = 10) Any particulate respirator equipped with an N95, R95, or P95 filter (including N95, R95, and P95 filtering facepieces) except quarter-mask respirators. The following filters may also be used: N99, R99, P99, N100, R100, P100.
Click here for information on selection of N, R, or P filters.
(APF = 10) Any supplied-air respirator

Up to 250 mg/m3:
(APF = 25) Any supplied-air respirator operated in a continuous-flow mode
(APF = 25) Any powered, air-purifying respirator with a high-efficiency particulate filter.

Up to 500 mg/m3:
(APF = 50) Any supplied-air respirator that has a tight-fitting facepiece and is operated in a continuous-flow mode
(APF = 50) Any powered, air-purifying respirator with a tight-fitting facepiece and a high-efficiency particulate filter
(APF = 50) Any air-purifying, full-facepiece respirator with an N100, R100, or P100 filter.
Click here for information on selection of N, R, or P filters.
(APF = 50) Any self-contained breathing apparatus with a full facepiece
(APF = 50) Any supplied-air respirator with a full facepiece

Up to 1500 mg/m3:
(APF = 1000) Any supplied-air respirator operated in a pressure-demand or other positive-pressure mode

Emergency or planned entry into unknown concentrations or IDLH conditions:
(APF = 10,000) Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode
(APF = 10,000) Any supplied-air respirator that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary self-contained positive-pressure breathing apparatus

Escape:
(APF = 50) Any air-purifying, full-facepiece respirator with an N100, R100, or P100 filter.
Click here for information on selection of N, R, or P filters.
Any appropriate escape-type, self-contained breathing apparatus

Important additional information about respirator selection

See also
INTRODUCTION   ICSC CARD: 1555

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