Diborane
Synonyms & Trade Names
Boroethane, Boron hydride, Diboron hexahydrideExposure Limits
NIOSH REL
TWA 0.1 ppm (0.1 mg/m3)OSHA PEL
TWA 0.1 ppm (0.1 mg/m3)Physical Description
Colorless gas with a repulsive, sweet odor. [Note: Usually shipped in pressurized cylinders diluted with hydrogen, argon, nitrogen, or helium.]Molecular Weight
27.7Boiling Point
-135°FFreezing Point
-265°FSolubility
ReactsVapor Pressure
(62°F): 39.5 atmIonization Potential
11.38 eVFlash Point
NA (Gas)Upper Exposive Limit
88%Lower Explosive Limit
0.8%Relative Gas Density
0.97Incompatibilities & Reactivities
Water, halogenated compounds, aluminum, lithium, oxidized surfaces, acids [Note: Will ignite spontaneously in moist air at room temperature. Reacts with water to form hydrogen & boric acid.]Exposure Routes
inhalationSymptoms
Chest tightness, precordial pain, short breath, nonproductive cough, nausea; headache, dizziness, chills, fever, lassitude (weakness, exhaustion), tremor, muscle fasciculation; In Animals: liver, kidney damage; pulmonary edema; hemorrhageTarget Organs
respiratory system, central nervous system, liver, kidneysPersonal Protection/Sanitation
(See protection codes)Skin:No recommendation
Eyes:No recommendation
Wash skin:No recommendation
Remove:No recommendation
Change:No recommendation
Respirator Recommendations
NIOSH/OSHA
Up to 1 ppm:
(APF = 10) Any supplied-air respirator
Up to 2.5 ppm:
(APF = 25) Any supplied-air respirator operated in a continuous-flow mode
Up to 5 ppm:
(APF = 50) Any supplied-air respirator that has a tight-fitting facepiece and is operated in a continuous-flow mode
(APF = 50) Any self-contained breathing apparatus with a full facepiece
(APF = 50) Any supplied-air respirator with a full facepiece
Up to 15 ppm:
(APF = 1000) Any supplied-air respirator operated in a pressure-demand or other positive-pressure mode
Emergency or planned entry into unknown concentrations or IDLH conditions:
(APF = 10,000) Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode
(APF = 10,000) Any supplied-air respirator that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary self-contained positive-pressure breathing apparatus
Escape:
(APF = 50) Any air-purifying, full-facepiece respirator (gas mask) with a chin-style, front- or back-mounted canister providing protection against the compound of concern
Any appropriate escape-type, self-contained breathing apparatus
- Page last reviewed:April 11, 2016
- Page last updated:April 11, 2016
- Content source:
- National Institute for Occupational Safety and Health (NIOSH) Education and Information Division