Hydrogen selenide
Synonyms & Trade Names
Selenium dihydride, Selenium hydrideExposure Limits
NIOSH REL
TWA 0.05 ppm (0.2 mg/m3)OSHA PEL
TWA 0.05 ppm (0.2 mg/m3)Physical Description
Colorless gas with an odor resembling decayed horseradish. [Note: Shipped as a liquefied compressed gas.]Molecular Weight
81.0Boiling Point
-42°FFreezing Point
-87°FSolubility
(73°F): 0.9%Vapor Pressure
(70°F): 9.5 atmIonization Potential
9.88 eVFlash Point
NA (Gas)Upper Exposive Limit
?Lower Explosive Limit
?Relative Gas Density
2.80Incompatibilities & Reactivities
Strong oxidizers, acids, water, halogenated hydrocarbonsExposure Routes
inhalation, skin and/or eye contactSymptoms
irritation eyes, nose, throat; nausea, vomiting, diarrhea; metallic taste, garlic breath; dizziness, lassitude (weakness, exhaustion); liquid: frostbite; In Animals: pneumonitis; liver damageTarget Organs
Eyes, respiratory system, liverPersonal Protection/Sanitation
(See protection codes)Skin:Frostbite
Eyes:Frostbite
Wash skin:No recommendation
Remove:When wet (flammable)
Change:No recommendation
Provide:Frostbite wash
Respirator Recommendations
NIOSH/OSHA
Up to 0.5 ppm:
(APF = 10) Any supplied-air respirator
Up to 1 ppm:
(APF = 25) Any supplied-air respirator operated in a continuous-flow mode*
(APF = 50) Any self-contained breathing apparatus with a full facepiece
(APF = 50) Any supplied-air respirator with a full facepiece
Emergency or planned entry into unknown concentrations or IDLH conditions:
(APF = 10,000) Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode
(APF = 10,000) Any supplied-air respirator that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary self-contained positive-pressure breathing apparatus
Escape:
(APF = 50) Any air-purifying, full-facepiece respirator (gas mask) with a chin-style, front- or back-mounted canister providing protection against the compound of concern¿
Any appropriate escape-type, self-contained breathing apparatus
- Page last reviewed:April 11, 2016
- Page last updated:April 11, 2016
- Content source:
- National Institute for Occupational Safety and Health (NIOSH) Education and Information Division