Malathion
Synonyms & Trade Names
Diethyl (dimethoxyphosphinothioylthio) succinate, S-[1,2-bis(ethoxycarbonyl) ethyl]O,O-dimethyl-phosphorodithioatePhysical Description
Deep-brown to yellow liquid with a garlic-like odor. [insecticide] [Note: A solid below 37°F.]Molecular Weight
330.4Boiling Point
140°F (Decomposes)Freezing Point
37°FSolubility
0.02%Vapor Pressure
0.00004 mmHgIonization Potential
?Specific Gravity
1.21Flash Point
(oc) >325°FUpper Exposive Limit
?Lower Explosive Limit
?Incompatibilities & Reactivities
Strong oxidizers, magnesium, alkaline pesticides [Note: Corrosive to metals.]Exposure Routes
inhalation, skin absorption, ingestion, skin and/or eye contactSymptoms
irritation eyes, skin; miosis, aching eyes, blurred vision, lacrimation (discharge of tears); salivation; anorexia, nausea, vomiting, abdominal cramps, diarrhea, dizziness, confusion, ataxia; rhinorrhea (discharge of thin nasal mucus), headache; chest tightness, wheezing, laryngeal spasmTarget Organs
Eyes, skin, respiratory system, liver, blood cholinesterase, central nervous system, cardiovascular system, gastrointestinal tractPersonal Protection/Sanitation
(See protection codes)Skin:Prevent skin contact
Eyes:Prevent eye contact
Wash skin:When contaminated
Remove:When wet or contaminated
Change:Daily
First Aid
(See procedures)Eye:Irrigate immediately
Skin:Soap wash promptly
Breathing:Respiratory support
Swallow:Medical attention immediately
Respirator Recommendations
NIOSH
Up to 100 mg/m3:
(APF = 10) Any air-purifying half-mask respirator with organic vapor cartridge(s) in combination with an N95, R95, or P95 filter. The following filters may also be used: N99, R99, P99, N100, R100, P100.
Click here for information on selection of N, R, or P filters.
(APF = 10) Any supplied-air respirator
Up to 250 mg/m3:
(APF = 25) Any supplied-air respirator operated in a continuous-flow mode*
(APF = 50) Any air-purifying full-facepiece respirator equipped with organic vapor cartridge(s) in combination with an N100, R100, or P100 filter.
Click here for information on selection of N, R, or P filters.
(APF = 50) Any air-purifying, full-facepiece respirator (gas mask) with a chin-style, front- or back-mounted organic vapor canister having an N100, R100, or P100 filter.
Click here for information on selection of N, R, or P filters.
(APF = 25) Any powered, air-purifying respirator with an organic vapor cartridge in combination with a high-efficiency particulate filter.*
(APF = 50) Any self-contained breathing apparatus with a full facepiece
(APF = 50) Any supplied-air respirator with a full facepiece
Emergency or planned entry into unknown concentrations or IDLH conditions:
(APF = 10,000) Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode
(APF = 10,000) Any supplied-air respirator that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary self-contained positive-pressure breathing apparatus
Escape:
(APF = 50) Any air-purifying, full-facepiece respirator (gas mask) with a chin-style, front- or back-mounted organic vapor canister having an N100, R100, or P100 filter.
Click here for information on selection of N, R, or P filters.
Any appropriate escape-type, self-contained breathing apparatus
- Page last reviewed:April 11, 2016
- Page last updated:April 11, 2016
- Content source:
- National Institute for Occupational Safety and Health (NIOSH) Education and Information Division